Solution:
- 1. Children, please behave yourselves! (Plural 'children' requires plural 'yourselves').
- 2. He hurt himself while he was skateboarding. ('He' requires 'himself').
- 3. I made this cake myself. ('I' requires 'myself').
- 4. The cat is looking at itself in the mirror. ('The cat', a singular non-human, requires 'itself').
- 5. We really enjoyed ourselves at the theme park. ('We' requires 'ourselves').
Final Answer: 1. yourselves, 2. himself, 3. myself, 4. itself, 5. ourselves