The question is: "When did he ... ?" This implies we're talking about an action that happened in the past.
We need to choose the correct past tense verb.
Let's look at the options:
'work' is the base form (present tense for most subjects).
'worked' is the simple past tense form.
'works' is the third-person singular present tense form.
Since the question starts with "When did he...?", it's asking about a past event. The auxiliary verb "did" already indicates the past tense, so the main verb should be in its base form. Therefore, "work" is the correct choice.