\[3(2a - b) - 5(a + 3b) =\]
\[= 6a - 3b - 5a - 15b =\]
\[= - a - 18b;\]
\[a = - 1;\ \ b = 5:\]
\[1 - 18 \cdot 5 = 1 - 90 = - 89.\]