\( \frac{1}{3} + \frac{3}{7} = \frac{1 \times 7}{3 \times 7} + \frac{3 \times 3}{7 \times 3} = \frac{7}{21} + \frac{9}{21} = \frac{16}{21} \)
\( 1 - \frac{16}{21} = \frac{21}{21} - \frac{16}{21} = \frac{5}{21} \)
\( 10 \text{ км} \div \frac{5}{21} = 10 \text{ км} \times \frac{21}{5} = \frac{10 \times 21}{5} = 2 \times 21 = 42 \text{ км} \)
Ответ: а) 42 км.